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One pot synthesis of pyrrolidines type 3,7-diazabicyclo [3.3.0] octane and biological activity

compounds (8b and 12a) were evaluated for antimicrobial (agar dilution method) and antioxidative (DPPH; 2,2-diphenyl-1-picrylhydrazyl and SOD; superoxide dismutase assays) activities. The results showed that [...] 2008-12-05T12:49:38Z dc.date.issued 2008-12-05T12:49:38Z dc.description.abstract Pyrrolidines type 2,4-disubstituted (alkyl, aryl or heteroaryl)-6,8-dioxo-3,7-diazabicyclo [3.3.0] octanes (8a-d) were [...] iso en de dc.relation.ispartofseries EXCLI Journal ; Vol. 7, 2008 en dc.subject 1-aminopyrrolidine-2,5-dione en dc.subject antimicrobial and antioxidative activities en dc.subject pyrrolidine en dc.subject …

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Reactions of N-acetylcysteine adducts of aromatic (di)isocyanates with functional groups of organic

of thiolate at pH 7.4, which is not possible in anhydrous DMAc. Reactions of (MDI(AcCys)2) are by a factor of 2 to 4 faster than those of pTI-AcCys. p-Toluidine (pTA) was found in the aqueous system due [...] Nacetylcysteine adducts of p-tolylisocyanate (pTI-AcCys) and 4,4’-diisocyanatodiphenyl- methane (MDI(AcCys)2) with N-acetylcysteine methyl ester (thiolysis), morpholine (aminolysis), methoxyethanol (alcoholysis) [...] Reaction rates and activation energies were determined for pTI in both media, reactions of MDI(AcCys)2 were run at one temperature only. Formation of insoluble reaction products and side reactions due to …

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